Korean Journal of Chemical Engineering, Vol.5, No.2, 116-122, September, 1988
ONE-FLUID MIXING RULES FOR CUBIC EQUATIONS OF STATE: II. SOLUBILITY OF SOLID MIXTURES IN SUPERCRITICAL FLUIDS
Three cubic equations of state are carefully examined to evaluate their capability for correlating the solubility of solid mixtures in supercritical fluids. After obtaining the pure solute-solvent interaction parameters, the solute-solute interaction parameters were directly calculated from the experimental ternary solubility data. The Redlich-Kwong, Soave, and Peng-Robinson equations of state correlate well the ternary data. However, the Redlich-Kwong equation of state gives the best result among them.