화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.27, No.5, 1560-1564, September, 2010
Preparation of sawdust functionalized with aspartic acid and its sorption capacity, kinetics and thermodynamics for basic dyes
E-mail:
An ion exchanger with carboxyl groups as active sites was prepared by activating sawdust with epichlorohydrin, followed by coupling the epoxy-activated sawdust with aspartic acid. The optimal sorption condition, sorption capacity, kinetics and thermodynamics of basic dyes on sawdust ion exchanger (SIE) from aqueous solution were investigated in a batch system. Two basic dyes, methylene blue (MB) and crystal violet (CV), were selected as sorbates. The optimal pH value of MB and CV solutions for favorable sorption was pH 4 and above. The removal ratios of MB and CV on SIE increased with increasing sorbent dose but decreased with increasing dye concentration. The isothermal data of MB and CV sorbed on SIE correlated basically with the Langmuir model. The maximum sorption capacity (Qm) of SIE for MB and CV was 222.22 and 232.56 mg/g, respectively. The sorption equilibriums of MB and CV on SIE were reached at about 9 h, and the sorption processes could be described by the pseudo-second-order kinetic model. The thermodynamic study indicated that the sorptions of MB and CV on SIE were spontaneous and endothermic at the predetermined temperatures. High temperatures were favorable for the sorption processes.
  1. Pearce CI, Lloyd JR, Guthrie JT, Dyes Pigments., 58, 179 (2003)
  2. McMullan G, Meehan C, Conneely A, Kirby N, Robinson T, Nigam P, Banat IM, Marchant R, Smyth WE, Appl. Microbiol. Biotechnol., 56(1-2), 81 (2001)
  3. McKay G, Otterburn MS, Aga DA, Water Air Soil Pollut., 24, 307 (1985)
  4. Gregory AR, Elliot S, Kluge P, J. Appl. Toxicol., 1, 308 (1991)
  5. Kim BK, Kim YH, Yamamoto T, Korean J. Chem. Eng., 25(5), 1140 (2008)
  6. Allen SJ, Gan Q, Matthews R, Johnson PA, Bioresour. Technol., 88, 143 (2003)
  7. Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90 (2005)
  8. Gong RM, Li M, Yang C, Sun YZ, Chen J, J. Hazard. Mater., 121(1-3), 247 (2005)
  9. Bulut Y, Aydin H, Desalination, 194(1-3), 259 (2006)
  10. Sulak MT, Demirbas E, Kobya M, Bioresour. Technol., 98(13), 2590 (2007)
  11. Kumar KV, Dyes Pigments., 74, 595 (2007)
  12. Osma JF, Saravia V, Toca-Herrera JL, Couto SR, J. Hazard. Mater., 147(3), 900 (2007)
  13. Hameed BH, El-Khaiary MI, J. Hazard. Mater., 154(1-3), 639 (2008)
  14. Hameed BH, Mahmoud DK, Ahmad AL, Colloid. Surface. A., 316, 78 (2008)
  15. Pavan FA, Lima EC, Dias SLP. Mazzocato AC, J. Hazard.Mater., 150, 703 (2008)
  16. Marchetti V, Gerardin P, Loubinoux B, Holz Roh Werkst., 58, 53 (2000)
  17. Gong RM, Jin YB, Chen FY, Chen J, Liu ZL, J. Hazard. Mater., 137(2), 865 (2006)
  18. Ong ST, Lee CK, Zainal Z, Bioresour. Technol., 98(15), 2792 (2007)
  19. Sureshkumar MV, Namasivayam C, Colloid. Surface. A., 317, 277 (2008)
  20. Disbudak A, Bektas S, Patir S, Genc O, Denizli A, Sep. Purif. Technol., 26(2-3), 273 (2002)
  21. Gupta SC, Dass P, Sharma P, Singh AV, Gupta S, Desalination, 143(2), 141 (2002)
  22. Oshita K, Oshima M, Gao Y, Lee KH, Motomizu S, Anal.Chim. Acta., 480, 239 (2003)
  23. Lei YL, Lin DQ, Yao SJ, Zhu ZQ, React. Funct. Polym., 62, 169 (2005)
  24. Chakraborty S, De S, DasGupta S, Basu JK, Chemosphere., 58, 1079 (2005)
  25. Vinod VP, Anirudhan TS, Water Air Soil Pollut., 150, 193 (2003)
  26. Porkodi K, Kumar KV, J. Hazard. Mater., 143(1-2), 311 (2007)