Melt-blown webs from ester and ether thermoplastic polyurethanes and polyether-block-amide (PEBA) elastomers were produced at different die-to-collector distances (DCD) to study the correlation between the polymer type and hardness, melt-blowing process conditions, and web properties. An experimental set up was built to measure the air temperature and velocity profiles below and across the melt-blowing die to correlate the fiber formation process and polymer crystallization behavior to process conditions and web properties. It was shown that air temperature and velocity profiles follow similar trends with increasing distance below the melt-blowing die: both drop rapidly until reaching a plateau region approximately 5-6 cm below the die. Thereafter, they remain relatively constant with further increasing distance. It was found that crystallization onset and peak temperatures of all block copolymers in this study fall within this region of rapid velocity and temperature drop. This suggests that the polymers have already started to crystallize and solidify before reaching the collector, the extent of which depends on the crystallization kinetics of the polymer. The strong influence of the crystallization kinetics on web strength was clearly demonstrated in the PEBA series. In particular, the hardest grade produced the lowest web strength mainly because of its high crystallization rate and crystallization onset temperature. It is concluded that the melt-blown web strength is strongly dependent on the degree of fiber-to-fiber adhesion within the web, which is determined by the amount of fiber solidification that occurs prior to the collector. The crystallization kinetics of the polymer and the distances traveled between the die and collector or the exposure time of the polymer melt to process and ambient air were shown to be critical in the amount of fiber solidification attained. POLYM. ENG. SCI., 49:1340-1349, 2009. (C) 2009 Society of Plastics Engineers