Powder Technology, Vol.190, No.1-2, 210-214, 2009
Stoichiometry and particle morphology effects on the aptitude to compaction of apatitic structure powders
Apatitic calcium phosphates powders with Ca/P molar ratio of 1.5 to 1.8 were synthesized at 25 degrees C using the neutralization method. These powders, differing by stoichiometry and particle morphology, were compacted in similar conditions. For a similar morphology of particles, compacts of the non-stoichiometric powders have better cohesion than those of the stoichiometric hydroxyapatite (Ca-10(PO4)(6)(OH)(2): Ca/P=11.67). The lacunar structure, with deficiency of calcium (Ca10-x (HPO4)(x)(PO4)(6-x)(OH)(2-x): 1.5