Primary kinetic isotope effect in the nitrosation of 1,3-dialkylureas

Gonzalez-Alatorre G; Perez-Mendez D; Godinez-Garcia A; Escamilla-Silva EM; Rico-Ramirez V

Reaction Kinetics and Catalysis Letters, Vol.96, No.1, 5-12, 2009

DOI10.1007/s11144-009-5398-7 Export Citation

Primary kinetic isotope effect in the nitrosation of 1,3-dialkylureas

Gonzalez-Alatorre G, Perez-Mendez D, Godinez-Garcia A, Escamilla-Silva EM, Rico-Ramirez V

In the nitrosation mechanism of 1,3 dialkylureas, the existence of protonic transfer to the solvent as a rate-limiting step was confirmed when a primary kinetic isotope effect was observed in these reactions.

Keywords:Primary kinetic isotope;1,3-dialkylureas