Rheologica Acta, Vol.47, No.4, 399-415, 2008
Mesoscopic formulation of reptation
Macromolecules stretch and bend. Their motion is moreover constrained (due to the presence of other macromolecules in their neighborhood) to a tube-like region. This well known physical picture is translated into governing equations on a new mesoscopic level of description by following the modular construction provided by GENERIC. Rheological predictions are calculated in both linear and nonlinear domains. A good agreement with results of experimental observations is found.