An application of a newly prepared TiO2 having anatase phase (A-700-1h) for decomposition of azo dye Acid Red 18 (AR18) in a photocatalytic membrane reactor (PMR), coupling photocatalysis and membrane distillation (MD) was investigated. The effectiveness of decomposition of the model dye using two commercially available TiO2 photocatalysts -ST-01 and P25 was also determined in order to compare the results. The A-700-1h catalyst was prepared from a crude amorphous TiO2 obtained directly from the production line (sulfate technology) at the Chemical Factory "Police" (Poland) by calcination for I h at 700 degrees C in air. The hybrid photocatalysis-MD process was conducted in a laboratory-scale installation with a capillary module equipped with polypropylene membranes. It was found that the initial degradation rate r(0) of AR18 using the A-700-1h catalyst was 49-64% higher than in case of anatase ST-01. Moreover, the effectiveness of decolorization of the dye solution at the A-700-1h loading of 0.5 g/dm(3) determined on the basis of r(0) value was only ca. 8% lower compared to the value determined for the P25 photocatalyst. Taking into account the composition of permeate it was found that only a small amount of by-products of dye photodecomposition was transported through the MID membrane. Moreover, a complete retention of the model dye was observed. (C) 2008 Elsevier B.V. All rights reserved.