화학공학소재연구정보센터
Separation Science and Technology, Vol.43, No.13, 3432-3447, 2008
Development of an All-ceramic Module with Silica Membrane Tubes for High Temperature Hydrogen Separation
Heat resistant hydrogen selective membranes are desired for use as membrane reactors in low-temperature hydrogen production via the steam reforming of hydrocarbons, which are usually operated over 1000 K. In addition, developing a multi-tubular type of membrane unit that can process more reactants is becoming more and more important in order to realize the practical use of membrane reactors. In this study, an all-ceramic module consisting of 6 silica membrane tubes with a comparatively large membrane area of around 0.04m(2) was fabricated by a counter-diffusion chemical vapor deposition technique. As a result, the H-2/N-2 ideal separation factor and the H-2 permeance of the module were 1300 and 1.9 x 10(-7) mol . m(-2)s(-1)Pa(-1) at 873 K, respectively. In a 1000-hour thermal stability test for the silica membrane module, it was found that the H-2 permeance initially decreased by about 30% and then became steady under Delta P = 0.95MPa at 773 K.