화학공학소재연구정보센터
Solid State Ionics, Vol.179, No.21-26, 780-782, 2008
Defect modes around low-lying phonon in Ag beta-alumina by Raman scattering with high resolution
Raman spectra for low-lying phonons of Ag beta-alumina were measured in the temperature range of 30 K-280 K. The broad band of the low-lying phonon was found to contain three Lorentz bands by a double monochrometer with high resolution (Delta E= 1 cm(-1)). Well resolved three bands correspond to the previous Raman results observed from the isornorphous beta-alumina of K, Tl or Rb. The decomposed low-lying phonon of Ag beta-alumina shows that the band width broadens with an increase in temperature clearly. The damping energy obtained from the Raman line-width of the low-lying phonon was estimated to be 0.51 meV at 30 K. It is in excellent agreement with the value 0.55 meV at 30 K from the femtosecond time-resolved observation [O. Kamishima, B. Paxton, T. Feurer, K.A. Nelson, Y. Iwai, J. Kawamura and T. Hattori, J. Phys.: Condensed Matter 19 (2007) 456215]. (C) 2008 Elsevier B.V. All rights reserved.