A series of monoclinic Li3V2(PO4)(3) cathode materials were prepared by H-2 reduction (LVP-H-2) and carbothermal reduction (LVP-CTR) methods. LVP-H-2 showed a primary particle size of about 1 mu m, which was much larger than the LVP-CTR samples. A uniform surface carbon layer was observed for the LVP-CTR samples by transmission electron microscope. This carbon layer not only limited the particle growth of the materials but also enhanced the material's electronic conductivity by five orders of magnitude. The LVP-CTR samples exhibited much better electrochemical performance than LVP-H-2. The good electrochemical performance of LVP-CTR was attributed to its nano particle size, high electronic conductivity, as well as the surface carbon layer which limited the vanadium dissolution in electrolyte. (c) 2009 Elsevier B.V. All rights reserved.