화학공학소재연구정보센터
AIChE Journal, Vol.55, No.12, 3255-3266, 2009
A Novel Dual Circulating Fluidized Bed System for Chemical Looping Processes
A fluidized bed system combining two circulating fluidized bed reactors is proposed and investigated for chemical looping combustion. Direct hydraulic communication of the two circulating fluidized bed reactors via a fluidized loop seal allows for high rates of global solids circulation and results in a stable solids distribution in the system. A 120 kW fuel power bench scale unit was designed, built, and operated. Experimental results are presented for natural gas as fuel using a nickel-based oxygen carrier. No carbon was lost to the air reactor under any conditions operated. It is shown from fuel power variations that a turbulent/fast fluidized bed regime in the fuel reactor is advantageous. Despite the relatively low riser heights (air reactor: 4.1 m, fuel reactor: 3.0 m), high CH4 conversion and CO2 yield of up to 98% and 94%, respectively, can be reported for the material tested. (C) 2009 American Institute of Chemical Engineers AIChE J, 55:3255-3266, 2009