DIFFUSIONAL INTERFERENCE IN LIQUID PHASE COUNTER-ADSORPTIONS

MOON H; PARK HC; LEE WK

Korean Journal of Chemical Engineering, Vol.7, No.4, 250-258, October, 1990

A surface diffusion model with diffusional interference has been presented for the analysis of multicomponent adsorption of phenols by activated carbon. Surface diffusion coefficients for multicomponent adsorptions were estimated from the relationship between the surface diffusion coefficient of each species and the surface coverage. The diffusional interference coefficients, W_ij were in the range of 0.4-0.9, which show that the introduction of diffusional interference is necessary to analyze multicomponent counter-adsorptions properly. The proposed model successfully simulates the behaviour of phenols-activated carbon system in a batch adsorber.

[References]

Desai NJ, Do DD, Chem. Eng. Commun., 34, 101 (1985)
Fritz W, Merk W, Schlunder EU, Chem. Eng. Sci., 36, 731 (1981)
Liapis AI, Rippin DWT, Chem. Eng. Sci., 32, 619 (1977)
Leyva-Ramos R, Geankoplis CJ, Chem. Eng. Sci., 40, 799 (1985)
Suzuki M, Fujii T, AIChE J., 28, 380 (1982)
Muraki M, Iwashima Y, Hayakawa T, J. Chem. Eng. Jpn., 15, 34 (1982)
Moon H, Lee WK, J. Colloid Interface Sci., 96, 162 (1983)
Neretneieks I, Chem. Eng. Sci., 31, 465 (1976)
Gillilind ER, Baddour RF, Perkinson GP, Sladek KJ, Ind. Eng. Chem. Fundam., 13, 95 (1974)
Okazaki M, Tamon H, Toei R, AIChE J., 27, 262 (1981)
Hasse R, "Thermodynamics of Irreversible Processes," Addison-Wesley, Darmstadt (1963)
Tien C, Chem. Eng. Commun., 40, 265 (1986)
Moon H, Tien C, Ind. Eng. Chem. Res., 26, 2042 (1987)
Fritz W, Schlunder EU, Chem. Eng. Sci., 36, 721 (1981)
von Rosenberg DU, "Method for the Numerical Solution of Partial Differential Equations," Elsevier, New York (1969)
Moon H, Ph.D. Thesis, Korean Advanced Institute of Science & Technology, Seoul, Korea (1984)
Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Jpn., 15, 67 (1982)
Peel RG, Benedek A, Crowe CM, AIChE J., 27, 26 (1981)
Reid RC, Prausnitz JM, Sherwood TK, "The Properties of Gases and Liquids," McGraw-Hill, New York (1977)
Mattson JS, Mark HB, "Activated Carbon: Surface Chemistry and Adsorption from Solution," Marcel Dekker, New York (1971)
Moon H, Lee WK, Chem. Eng. Sci., 41, 1995 (1986)
Wang SC, Tien C, AIChE J., 28, 565 (1982)
Seo G, Moon H, Korean J. Chem. Eng., 2(2), 173 (1985)

[Referenced By]

[1] Desai NJ, Do DD, Chem. Eng. Commun., 34, 101 (1985)

[2] Fritz W, Merk W, Schlunder EU, Chem. Eng. Sci., 36, 731 (1981)

[3] Liapis AI, Rippin DWT, Chem. Eng. Sci., 32, 619 (1977)

[4] Leyva-Ramos R, Geankoplis CJ, Chem. Eng. Sci., 40, 799 (1985)

[5] Suzuki M, Fujii T, AIChE J., 28, 380 (1982)

[6] Muraki M, Iwashima Y, Hayakawa T, J. Chem. Eng. Jpn., 15, 34 (1982)

[7] Moon H, Lee WK, J. Colloid Interface Sci., 96, 162 (1983)

[8] Neretneieks I, Chem. Eng. Sci., 31, 465 (1976)

[9] Gillilind ER, Baddour RF, Perkinson GP, Sladek KJ, Ind. Eng. Chem. Fundam., 13, 95 (1974)

[10] Okazaki M, Tamon H, Toei R, AIChE J., 27, 262 (1981)

[11] Hasse R, "Thermodynamics of Irreversible Processes," Addison-Wesley, Darmstadt (1963)

[12] Tien C, Chem. Eng. Commun., 40, 265 (1986)

[13] Moon H, Tien C, Ind. Eng. Chem. Res., 26, 2042 (1987)

[14] Fritz W, Schlunder EU, Chem. Eng. Sci., 36, 721 (1981)

[15] von Rosenberg DU, "Method for the Numerical Solution of Partial Differential Equations," Elsevier, New York (1969)

[16] Moon H, Ph.D. Thesis, Korean Advanced Institute of Science & Technology, Seoul, Korea (1984)

[17] Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Jpn., 15, 67 (1982)

[18] Peel RG, Benedek A, Crowe CM, AIChE J., 27, 26 (1981)

[19] Reid RC, Prausnitz JM, Sherwood TK, "The Properties of Gases and Liquids," McGraw-Hill, New York (1977)

[20] Mattson JS, Mark HB, "Activated Carbon: Surface Chemistry and Adsorption from Solution," Marcel Dekker, New York (1971)

[21] Moon H, Lee WK, Chem. Eng. Sci., 41, 1995 (1986)

[22] Wang SC, Tien C, AIChE J., 28, 565 (1982)

[23] Seo G, Moon H, Korean J. Chem. Eng., 2(2), 173 (1985)