Applied Surface Science, Vol.256, No.9, 2927-2933, 2010
Effects of UV-irradiation on the thermo-mechanical properties of optical grade poly(methyl methacrylate)
We studied the evolution of the thermo-mechanical properties of poly(methyl methacrylate) (PMMA) materials exposed to ultra-violet (UV) light. To do so we measured important mechanical parameters including the fracture strength, the stress-strain relation, and Young's modulus as a function of the UV-irradiation dose. We concluded that the mechanical properties of PMMA are affected by UV light. The ductility disappears and the strength and strain at rupture strongly decrease (over 30%). The evolution of the Young's modulus is discussed as a function of the cross-linking degree of the materials. Moreover we observed the occurrence of surface damage, which in its turn enhances the degradation of these mechanical parameters. (C) 2009 Elsevier B. V. All rights reserved.
Keywords:Poly(methyl methacrylate);UV-irradiation;Photo-chemical degradation;Mechanical properties;Damage evolution