화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.36, No.5, 1535-1543, 1997
Biomass Gasification with Steam in Fluidized-Bed - Effectiveness of CaO, MgO, and CaO-MgO for Hot Raw Gas Cleaning
The upgrading of the raw hot gas from a bubbling fluidized bed biomass gasifier is studied using cheap calcined minerals or reeks downstream from the gasifier. Biomass gasification is made with steam (not air) at 750-780 degrees C and about 0.5-1.0 kg of biomass/h. Calcined solids used are dolomite (MgO-CaO), pure calcite (CaO), and pure magnesite (MgO). Variables studied have been temperature of the secondary bed (780-910 degrees C), time of contact or space-time of the gas (0.08-0.32 kg.h/m(3)n), and particle diameter (1-4 mm) and type of mineral. Their effects on tar conversion, tar amount in the exit gas, product distribution, and gas composition are presented. Using a macrokinetic model for the tar disappearance network, the activities of the stones are expressed by their apparent kinetic constant. Apparent energies of activation for tar elimination (42-47 kJ/mol) and preexponential and effectiveness factors are given for all tested solids of which the most active is the calcined dolomite.