화학공학소재연구정보센터
Applied Surface Science, Vol.257, No.1, 232-238, 2010
Deposition of quasi-crystal Al-doped ZnO thin films for photovoltaic device applications
Quasi-crystal aluminum-doped zinc oxide (AZO) films were prepared by in situ radio frequency (RF) magnetron sputtering (sputtering without annealing) on glass substrates. The influence of deposition parameters on the optoelectronic and structural properties of the in situ deposited quasi-crystal AZO films was investigated in order to compare resulting samples. X-ray diffraction (XRD) patterns show that the quasi-crystal AZO thin films have excellent crystallization improved with increase of the RF power and substrate temperature, with an extremely preferential c-axis orientation exhibit sharp and narrow XRD pattern similar to that of single-crystal. Field emission scanning electron microscopy (FESEM) images show that quasi-crystal AZO thin films have uniform grains and the grain size increase with the increase of RF power and substrate temperature. Craters of irregular size with the columnar structure are observed in the quasi-crystal AZO thin films at a lower substrate temperature while many spherical shaped grains appeared at a higher substrate temperature. The average optical transmittance of all the quasi-crystal AZO films was over 85% in the 400-800nm wavelength range. The resistivity of 4.176 x 10(-4) Omega cm with the grain size of 76.4891 nm was obtained in the quasi-crystal AZO thin film deposited at 300 degrees C, under sputtering power of 140 W. (C) 2010 Elsevier B. V. All rights reserved.