Catalysis Reviews-Science and Engineering, Vol.51, No.3, 325-440, 2009
Water Gas Shift Catalysis
Developments in water gas shift (WGS) catalysis, especially during the last decade, are reviewed. Recent developments include the development of 1 chromium-free catalysts that can operate at lower steam to gas ratios and 2 more active catalysts that can operate at gas hourly space velocities above 40,000h-1. A current challenge is to develop catalysts for use in fuel cell applications. Precious metal catalysts supported on partially reducible oxide supports (Pt-ceria, Pt-titania, Au-ceria, etc.) are the current front runners. A critical review of the mechanism of the WGS reaction is also presented.
Keywords:Water gas shift;Hydrogen production;CO conversions;Fuel processor;Fuel cell;Iron oxide catalysts;Copper-Zinc oxide catalysts;Pt catalysts;Redox mechanism;Formate mechanism;High temperature shift;Low temperature shift;Sour gas shift;Chromium-free catalysts