Particles are often electrostatically charged by frictional contact during powder-handling operations. This phenomenon is called 'triboelectric charging' or 'contact electrification'. The charged particles cause problems such as particle deposition and adhesion. In addition, if particles are excessively charged, an electrostatic discharge may occur, which can pose a risk of fire and explosion hazards; thus, to mitigate the adverse effects, it is important to elucidate the underlying triboelectric charging mechanisms. The electrostaticsis, on the other hand, very useful in a number of applications that have been developed using the principles. In this review, the basic concepts and theories of charge transfer between solid surfaces are summarized, and chemical factors depending on materials and environmental effects are described. To theoretically analyze the process of particle charging, relevant models are discussed. Using the models, particle charging by repeated impacts on a wall is formulated. To experimentally evaluate particle charging, measurement and characterization methods are outlined. Furthermore, important applications and computer simulations are described. (C) 2010 Elsevier Ltd. All rights reserved.