Catalytic oxidation of ammonia in supercritical water (SCW) was studied using a continuous-flow, packed-bed reactor at temperatures ranging from 410 to 470 degrees C, a nominal pressure of 27.6 MPa, and reactor residence times of less than 1 s. The kinetics and catalyst performance of MnO2/CeO2 for oxidation of ammonia in SCW was evaluated. In this reaction environment, ammonia was predominantly converted into molecular nitrogen (N-2), and the rate of ammonia conversion was enhanced by MnO2/CeO2. For example, 40% of the ammonia was converted when using the MnO2/CeO2 catalyst at a temperature of 450 degrees C and a reactor residence time of 0.8 s. It was reported that, nithout a catalyst, essentially no ammonia conversion was observed below 525 degrees C (Helling, R. K.; Tester, J. W. Environ. Sci. Technol. 1988, 22 (11), 1319) and 10% of the ammonia was converted at a temperature of 680 degrees C, a pressure of 24.6 MPa, and a reactor residence time of 10 s (Webley, P. A.; Tester, J. W.; Holgate, H. R. Ind. Eng. Chem. Res. 1991, 30 (8), 1745). Kinetic models developed for the gas-phase catalytic oxidation of ammonia were adopted and proven to be adequate for catalytic oxidation of ammonia in supercritical water. The best-fit global rate expression for catalytic supercritical water oxidation of ammonia by MnO2/CeO2 was obtained as follows : r = 1.14 x 10(14) exp(-189 kJ/mol/RT) [NH3](0.63)[O-2](0.71). The BET surface area and X-ray diffraction analyses of the exposed catalyst indicated a significant reduction of surface area and changes in the crystalline structure of the catalyst.