Chemistry Letters, Vol.39, No.6, 564-566, 2010
Detection of the Heterochirality of a 1:2 Metal/Ph-pybox Complex Ion by ESIMS
The heterochirality of a 1:2 metal/Ph-pybox complex ion was encyclopedically evaluated by ESIMS using pseudo-racemic (R,R)- and (S,S)-Ph-pybox pair, which were unlabeled/labeled by deuterium atoms, respectively. The heterochiral complex was predominantly formed in all investigated 1:2 metal/Ph-pybox complex ions.