화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.16, No.6, 962-966, November, 2010
DOI10.1016/j.jiec.2010.04.004  Export Citation
High pressure phase behavior for the propionitrile and butyronitrile in supercritical carbon dioxide
Sung-Hyun Kim, Mi-Hwa Park, Jong-Sung Lim1, and Hun-Soo Byun†
  • School of Biotechnology and Chemical Engineering, Chonnam National University, Yeosu, Jeonnam 550-749, South Korea
  • 1Department of Chemical and Biomolecular Engineering, Sogang University, Seoul 121-742, South Korea
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Pressure-composition isotherms for the (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems are measured in static-type high pressure apparatus at several temperatures of 313.2, 333.2, 353.2, 373.2 and 393.2 K and at pressures range from 3.5 to 16.7 MPa. The carbon dioxide + nitriles systems have continuous critical mixture (local) curves that exhibit maximums in pressure-temperature space between the critical point of carbon dioxide and monomers (propionitrile or butyronitrile). At a fixed pressure, the solubility of propionitrile or butyronitrile for the two binary systems increases as the temperature increases. The (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems exhibit type-I phase behavior. The experimental results for the (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems are correlated with Peng-Robinson equation of state using mixing rule including two adjustable parameters.
Keywords:Carbon dioxide;Propionitrile;Butyronitrile;High pressure phase behavior
  1. Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)
  2. Jung J, Perrut M, J. Supercrit. Fluids, 20(3), 179 (2001)
  3. Waegemaekers THJ, Bensink MMPM, Mutat. Res., 137, 95 (1984)
  4. Lora M, McHugh MA, Fluid Phase Equilib., 157(2), 285 (1999)
  5. Byun HS, Lee DH, Ind. Eng. Chem. Res., 45(10), 3373 (2006)
  6. Rezende RP, Teixeira Dias JC, Monteiro AS, Carraza F, Linardi VR, Braz. J. Microbiol., 34, 117 (2003)
  7. Byun HS, Kim YS, Im JK, J. Korean Ind. Eng. Chem., 9(6), 924 (1998)
  8. Park SJ, Oh JH, Choi HJ, Paek SK, Fischer K, Gmehling J, Korean Chem. Eng. Res., 35, 678 (1997)
  9. Byun HS, Hasch BM, McHugh MA, Fluid Phase Equilib., 115(1-2), 179 (1996)
  10. Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
  11. Reid RC, Prausnitz JM, Polling BE, The Properties of Gases and Liquid, 4th ed., McGraw-Hill, New York (1987)
  12. Byun HS, Shin JS, J. Chem. Eng. Data., 48, 97 (2003)
  13. McHugh MA, Krukonis VJ, Supercritical Fluid Extraction: Principles and Practice, Butterworth, Boston, MA (1994)
  14. Scott RL, van Konynenburg PB, Discuss. Faraday Soc., 49, 87 (1970)
  15. Kuester JL, Mize JH, Optimization Techniques with Fortran, McGraw-Hill, New York (1973)
  16. Daubert TE, Danner RP, Physical and Thermodynamic Properties of Pure Chemicals, Hemishere Publishing Corp., New York (1989)