Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition

Hamit Yurtseven; Yesin Dildar

Korean Journal of Chemical Engineering, Vol.28, No.1, 252-255, January, 2011

DOI10.1007/s11814-010-0320-6 Export Citation

Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition

Hamit Yurtseven^†, and Yesin Dildar

Department of Physics, Middle East Technical University, 06531, Ankara-Turkey

E-mail:

We calculate the thermal expansion α(p), isothermal compressibility κ(T) and the specific heat, C(p)-C(v), as a function of pressure using the observed V-P data at room temperature close to the III-IV phase transition in CCl(4). Calculated κ(T), α(p) and C(p)-C(v) decrease as the pressure increases from phase III to phase IV in this molecular crystal system, as expected. On the basis of our calculations of the κ(T), α(p) and C(p)-C(v), the Pippard relations are established close to the III-IV phase transition in CCl(4), which can be verified experimentally.

Keywords:Pippard Relations;Phase Transition;CCl(4)

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[1] Rudman R, Post B, Science., 154, 1009 (1966)

[2] Weir CE, Piermarini GJ, Block S, J. Chem. Phys., 50, 2424 (1969)

[3] Piermarini GJ, Braun AB, J. Chem. Phys., 58, 1974 (1973)

[4] Cohen S, Powers R, Rudman R, Acta Cryst. B., 35, 1670 (1979)

[5] Adams DM, Sharma SK, J. Chem. Soc. Dalton Trans., 2089 (1976)

[6] Kawamura H, Kobayashi M, Yamamato Y, Matsui N, Akahama Y, Solid State Commnu., 102, 501 (1997)

[7] Kotake K, Nakamura N, Chihara H, Bull. Chem. Soc. Jpn., 40, 1018 (1967)

[8] Silvera L, Rudman R, J. Phys. Chem., 74, 3134 (1970)

[9] Arentsen JG, van Miltenburg JC, J. Chem. Thermodyn., 4, 789 (1972)

[10] Morrison JA, Richards EL, J. Chem. Thermodyn., 8, 1033 (1976)

[11] Badiali JP, Bruneaux-Poulle J, Defrain A, J. Chem. Phys., 73, 113 (1976)

[12] Maruyama M, Kawabata K, Kuribayashi N, J. Cryst. Growth., 200, 161 (2000)

[13] Bean VE, Wood SD, J. Chem. Phys., 72, 5838 (1980)

[14] Xans P, Saint-Gurions H, Dumas JP, J. Phys. C., 10, L267 (1977)

[15] Weber WJ, Goodstein DL, Phys. Rev. B., 73, 195424 (2006)

[16] Koga Y, Morrison JA, J. Chem. Phys., 62, 3359 (1975)

[17] Andersen A, Torrie BH, Tse WS, Chem. Phys. Lett., 61, 119 (1979)

[18] Djabourov M, Levy-Manneheim C, Leblond J, Papon P, J.Chem. Phys., 66, 5748 (1975)

[19] Zuk JD, Kiefte H, Clouler MJ, J. Chem. Phys., 95, 1950 (1991)

[20] Pruzan P, Liebenberg DH, Mills RL, J. Phys. Chem. Solids., 47, 949 (949)

[21] Kavruk DK, Yurtseven H, High Temp. Mater. Processes., 26, 397 (2007)

[22] Yurtseven H, Kavruk D, J. Mol. Liq., 139, 117 (2008)

[23] Yurtseven H, Kavruk D, Mod. Phys. Lett. B., 24, 75 (2010)

[24] Ebisuzaki Y, J. Raman Spect., 8, 331 (1979)