화학공학소재연구정보센터
Combustion Science and Technology, Vol.183, No.1, 1-19, 2011
An Instability of Diluted Lean Methane/Air Combustion: Modeling and Control
In order to study possibilities of Model Predictive Control (MPC) to low temperature combustion, the authors performed a numerical study of combustion with a lean highly diluted methane/air mixture in a perfectly stirred reactor using a detailed chemical kinetic model. Chosen conditions are the following: equivalence ratio 0.6, residence time of mixture in reactor 0.5s; molar fraction of Nitrogen 0.9, temperature of incoming unburned gases and reactor 1100K, and heat loss coefficient 2x10-3cal/(cm2Ks). At these conditions strong oscillations are predicted in agreement with previous experimental findings of M. de Joannon et al. (2004). It is found that, at low temperatures (1300K), reactions forming CH3O and CH3O2 from CH3 had a strong influence on the oscillations. Once these reactions were subtracted from the kinetic model, no oscillations were observed. A virtual MPC suppressed the oscillations at low temperatures successfully and demonstrated extremely low NO and N2O emissions (0.1ppm).