EFFECT OF ULTRASOUND ON SULFURIC ACID-CATALYSED HYDROLYSIS OF STARCH

Choi JH; Kim SB

Korean Journal of Chemical Engineering, Vol.11, No.3, 178-184, July, 1994

The influence of ultrasound on the hydrolysis of starch was investigated at moderate temperature range(90-100℃)and in the dilute sulfuric acid(1-5wt%). Enhancements of the reaction rate by ultrasound was observed. The degree of the relative enhancement depended on the reaction temperature. The model reaction by maltose showed that the acid hydrolysis of glucosidic linkages was first order with respect to the substance concentration and the hydrogen ion concentration, respectively. And the activation energies of the control and the ultrasound-aided hydrolysis of maltose were 30.2 and 23.4 kcal/mol, respectively. Enhancement was thus expressed as the alleviation of activation energy by ultrasound irradiation.

[References]

Mestres C, Colonna P, Buleon A, J. Food Sci., 53(6), 1809 (1988)
Hughes JF, U.S. Patent, 4,221,609 (1980)
Muller WC, Miller FD, U.S. Patent, 4,448,881 (1984)
Assarsson PG, Nagasuye JH, U.S. Patent, 4,469,524 (1984)
Muller WC, Miller FD, U.S. Patent, 4,407,955 (1983)
Muller WC, Miller FD, U.S. Patent, 4,421,856 (1983)
Banks W, Greenwood CT, Muir DD, Die Starke, 25(12), 405 (1973)
Faithfull NT, J. Sci. Food Agric., 50, 419 (1990)
Muller WC, Miller FD, U.S. Patent, 4,266,027 (1981)
Chen JW, Kalback WM, Ind. Eng. Chem. Fundam., 6(2), 175 (1967)
Jarowenko W, "Encyclopedia of Chemical Technology," vol. 12, pp. 787, edited by Mark, H.F., Othmer, D.F., Overberger, C.G. and Seaborg, G.T., Kirk-Othmer, A Wiley-Interscience Pub., John Wiley & Sons, NY (1983)
Kristol DS, Khamis AA, Parker RC, Ind. Eng. Chem. Prod. Res. Dev., 23, 74 (1984)
Schuchardt U, Joekes I, Duarrte HC, J. Chem. Technol. Biotechnol., 39, 155 (1987)
Whistler RL, "Starch: Chemistry and Technology," Vol. 1, pp. 1, edited by Whistler, R.L. and Paschell, E.F., Academic Press Inc., New York (1965)
Nakamura A, Tsutsui M, "Principle and Applications of homogeneous Catalysis," John Wiley & Sons, New York (1980)
Cox RA, Yates K, J. Am. Chem. Soc., 100(12), 3861 (1978)
Pethrick RA, "Advances in Sonochemistry," Vol. 2, pp. 65, edited by Mason, T.J., JAI Press Ltd. (1991)

[Referenced By]

[1] Mestres C, Colonna P, Buleon A, J. Food Sci., 53(6), 1809 (1988)

[2] Hughes JF, U.S. Patent, 4,221,609 (1980)

[3] Muller WC, Miller FD, U.S. Patent, 4,448,881 (1984)

[4] Assarsson PG, Nagasuye JH, U.S. Patent, 4,469,524 (1984)

[5] Muller WC, Miller FD, U.S. Patent, 4,407,955 (1983)

[6] Muller WC, Miller FD, U.S. Patent, 4,421,856 (1983)

[7] Banks W, Greenwood CT, Muir DD, Die Starke, 25(12), 405 (1973)

[8] Faithfull NT, J. Sci. Food Agric., 50, 419 (1990)

[9] Muller WC, Miller FD, U.S. Patent, 4,266,027 (1981)

[10] Chen JW, Kalback WM, Ind. Eng. Chem. Fundam., 6(2), 175 (1967)

[11] Jarowenko W, "Encyclopedia of Chemical Technology," vol. 12, pp. 787, edited by Mark, H.F., Othmer, D.F., Overberger, C.G. and Seaborg, G.T., Kirk-Othmer, A Wiley-Interscience Pub., John Wiley & Sons, NY (1983)

[12] Kristol DS, Khamis AA, Parker RC, Ind. Eng. Chem. Prod. Res. Dev., 23, 74 (1984)

[13] Schuchardt U, Joekes I, Duarrte HC, J. Chem. Technol. Biotechnol., 39, 155 (1987)

[14] Whistler RL, "Starch: Chemistry and Technology," Vol. 1, pp. 1, edited by Whistler, R.L. and Paschell, E.F., Academic Press Inc., New York (1965)

[15] Nakamura A, Tsutsui M, "Principle and Applications of homogeneous Catalysis," John Wiley & Sons, New York (1980)

[16] Cox RA, Yates K, J. Am. Chem. Soc., 100(12), 3861 (1978)

[17] Pethrick RA, "Advances in Sonochemistry," Vol. 2, pp. 65, edited by Mason, T.J., JAI Press Ltd. (1991)