화학공학소재연구정보센터
Electrochemical and Solid State Letters, Vol.13, No.11, G91-G94, 2010
Hydrogen-Induced Degradation in Physical Properties of Dielectric-Enhanced Ba0.6Sr0.4TiO3/SrTiO3 Artificial Superlattices
Dielectric-enhanced oxide superlattices that comprise Ba0.6Sr0.4TiO3 (BST) 6 nm/SrTiO3 (STO) 6 nm bilayers with 10 periods were grown epitaxially on Nb-doped STO(100) substrates. The lattice strain enhanced the dielectric properties and tunability of the as-deposited BST/STO superlattice. However, forming gas annealing degraded the electrical properties of the BST/STO superlattice. This change can be attributed to a loss of oxygen from the oxide films and the incorporation of hydrogen atoms into the lattice of oxides during the forming gas annealing. Subsequent oxygen-recovery annealing slightly improves the electrical characteristics of the superlattice because the largest possible number of hydrogen atoms was eliminated from the superlattice. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3477940] All rights reserved.