MWCNT-PSS/PEDOT/MnO2 nano-composite electrodes were fabricated by generating pseudo-capacitive poly(3,4-ethylenedioxythiophene) (PEDOT)/MnO2 nano-structures on poly(styrene sulfonate) (PSS) dispersed multiwalled carbon nanotubes (MWCNTs). PSS dispersed MWCNTs (MWCNT-PSS) facilitated the growth of PEDOT and MnO2 into nano-rods with large active surface area and good electrical conductivity. The ternary MWCNT-PSS/PEDOT/MnO2 nano-composite electrode was studied for the application in super-capacitors, and exhibited excellent capacitive behavior between -0.2V and 0.8V (vs. saturated Ag/AgCl electrode) with high reversibility. Specific capacitance of the nano-composite electrode was found as high as 375 Fg(-1). In contrast, specific capacitance of MWCNT-PSS/MnO2 and MWCNT-PSS nano-composite electrodes is 175 Fg(-1) and 15 Fg(-1), respectively. Based on cyclic voltammetric studies and cycle-life tests, the MWCNT-PSS/PEDOT/MnO2 nano-composite electrode gave a highly stable and reversible performance up to 2000 cycles. Our studies demonstrate that the synergistic combination of MWCNT-PSS, PEDOT and MnO2 has advantages over the sum of the individual components. (C) 2009 Elsevier Ltd. All rights reserved.