In this paper we report the zinc oxide nanorods (ZnO NRs) growth by electrochemical deposition onto polycrystalline gold electrodes modified with assemblies of polystyrene sphere monolayers (PSSMs) Growth occurs through the interstitial spaces between the hexagonally close packed spheres. ZnO NRs nucleate in the region where three adjacent spheres leave a space. being able to grow and projected over the PSSMs. The nanorod surface density (N-NR) shows a linear dependence with respect to a PS sphere diameter selected. XRD analysis shows these ZnO NRs are highly oriented along the (002) plane (c-axis). This open the possibility to have electronic devices with mechanically supported nanometric materials (C) 2009 Elsevier Ltd All rights reserved