Industrial & Engineering Chemistry Research, Vol.38, No.4, 1625-1632, 1999
Carbon dioxide-sustained adsorption of lactic acid at pH > pK(a) of the acid
Experimental data are presented for batch and fixed-bed adsorption of lactic acid from aqueous sodium lactate solutions onto the tertiary amine sorbents, Dowex MWA-1 and Amberlite IRA-35, in the presence of carbon dioxide. The effects of carbon dioxide pressure and sodium lactate concentration on lactate uptake capacity were measured. A simple complexation model, which includes chemical-equilibria and mass- and charge-balance equations, was developed to describe the system. There are no fitted parameters in the model. The model predictions compare well with batch adsorption data.
Keywords:CARBOXYLIC-ACIDS;AMINE EXTRACTANTS;ORGANIC-SOLVENT;FERMENTATION;EQUILIBRIA;SORBENTS;WATER;BASE