TEST OF SOME CHLORIDES AND ACTIVATED CARBONS AS CATALYSTS FOR CHLORINATION OF HCFC-133a

Shim GI; Yoon KJ; Kim HS; Park KY

Korean Journal of Chemical Engineering, Vol.12, No.4, 494-496, September, 1995

Chlorination of HCFC-133a with chlorine was performed over silica-supported NiCl₂, CuCl₂, MnCl₂, and KCl as well as over some activated carbons. The results were compared with those from the thermal chlorination and from other studies. The chlorides tested were found not to practically act as effective catalysts for the chlorination of HCFC-133a to HCFC-123 contrary to the claims in earlier works, and the activated carbons exhibited poorer HCFC-123 yields than the chlorides.

Keywords:Carbons;Chlorides;Chlorination;HCFC-133a

[References]

Cremer HR, Gunter S, Japan Patent, 91-52832 (Kokai) (1991)
Cremer HR, Gunter S, Deutsch. Patent, 3923248 (1989)
Kang SH, Lee TJ, Bae KS, Ahn HK, Kim YK, HWAHAK KONGHAK, 27(4), 404 (1989)
Kotaka Y, Homoto Y, Honda T, Japan Patent, 89-290638 (Kokai) (1989)
Levenspiel O, "Chemical Reaction Engineering," 2nd ed., pp. 185-195, Wiley, New York (1972)
Lim JG, Chang WC, Lee TJ, Shim JJ, Choi DK, Lee YY, HWAHAK KONGHAK, 32(3), 341 (1994)
McBee ET, Hass HB, Bittenbender WA, Weesner WE, Toland WG, Hausch WR, Frost LW, Ind. Eng. Chem., 39(3), 409 (1947)
Nakagawa S, Sato H, Watanabe K, J. Chem. Eng. Data, 36(2), 156 (1991)
Yoon KJ, Shim GI, Park KY, Kim HS, Korean J. Chem. Eng., 10(4), 220 (1993)

[Referenced By]

[1] Cremer HR, Gunter S, Japan Patent, 91-52832 (Kokai) (1991)

[2] Cremer HR, Gunter S, Deutsch. Patent, 3923248 (1989)

[3] Kang SH, Lee TJ, Bae KS, Ahn HK, Kim YK, HWAHAK KONGHAK, 27(4), 404 (1989)

[4] Kotaka Y, Homoto Y, Honda T, Japan Patent, 89-290638 (Kokai) (1989)

[5] Levenspiel O, "Chemical Reaction Engineering," 2nd ed., pp. 185-195, Wiley, New York (1972)

[6] Lim JG, Chang WC, Lee TJ, Shim JJ, Choi DK, Lee YY, HWAHAK KONGHAK, 32(3), 341 (1994)

[7] McBee ET, Hass HB, Bittenbender WA, Weesner WE, Toland WG, Hausch WR, Frost LW, Ind. Eng. Chem., 39(3), 409 (1947)

[8] Nakagawa S, Sato H, Watanabe K, J. Chem. Eng. Data, 36(2), 156 (1991)

[9] Yoon KJ, Shim GI, Park KY, Kim HS, Korean J. Chem. Eng., 10(4), 220 (1993)