Journal of Applied Polymer Science, Vol.115, No.5, 2865-2874, 2010
NaOH/Urea Aqueous Solutions Improving Properties of Regenerated-Cellulosic Fabrics
The application of sodium hydroxide and sodium hydroxide containing urea solutions has been utilized for regenerated-cellulosic material activation. The treatments resulted in the reorganization of cellulose fibers, hence accessibility and reactivity. In this study, sodium hydroxide-urea solutions were applied to lyocell and viscose-knitted fabrics as finishing treatment to improve the accessibility and physical properties of textiles. Besides the mixtures, different concentrations of sole sodium hydroxide and sole urea treatment were applied. The different concentrations of urea, sodium hydroxide, and sodium hydroxide-urea mixtures were used with small increment to detect suitable concentrations and mixture ratios applied for fabrics modification. The results showed the effectiveness of applying the mixture solutions of alkali-urea particularly to CV-knitted fabrics for improving pilling behavior, whereas for CLY fabrics, the standard alkali solutions showed the best pilling performance. The utilization of urea and sodium hydroxide-urea mixture played an important role for regenerated-cellulosic fabrics where high alkali concentrations is not preferred to avoid fabric damages and where a mixture system could inhibit some of these aspects. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 115: 2865-2874, 2010