Inorganic Chemistry, Vol.33, No.7, 1245-1246, 1994
Mixed-Metal Trinuclear Complexes Containing 2 Ruthenium(III) Ions and a Divalent Metal-Ion, (Ru2M(Mu-3-O)(Mu-Ch3Coo)6(L)3) (M=mg, Mn, Co, Ni, Zn, L=h2O, Pyridine)
The 10 new mixed-metal title complexes have been prepared through a new general synthetic approach tm the mixed-metal complex with the very common trinuclear structural unit. Their magnetic, UV-vis spectral, and redox behavior show that a divalent metal ion (M) acts as if an isolated ion and two d5 Ru(III) ions and mu3-O interact strongly within this portion, and that the Ru-M interaction is less significant.
Keywords:MANGANESE COMPLEXES