화학공학소재연구정보센터
Journal of Applied Electrochemistry, Vol.40, No.4, 855-864, 2010
Characterization of an electrochemical reactor for the ozone production in electrolyte-free water
The filter-press electrochemical ozonizer is characterized as a function of the applied electric current, temperature, and linear velocity of the electrolyte-free water. Lead dioxide electroformed on surface of a non-platinized fine mesh stainless steel support was used as anode. Electrolysis of the electrolyte-free water was carried out using the membrane electrode assembly (MEA) adequately compressed by means of a specially designed clamping system. Electrochemical characterization studies were carried out galvanostatically as a function of temperature and linear velocity of the circulating water. It was verified that the electrochemical ozone production (EOP) taking place at the reacting zones formed at the solid polymer electrolyte (SPE)/mesh electrode interface is not considerably affected by circulating water when the linear velocity inside the distribution channels is higher than 1.20 cm s(-1). A current efficiency for the EOP of 13% and a specific electric energy consumption of 70 Wh g(-1) were obtained when an electric current of 130 A was applied at 30 degrees C. The reactor service life test revealed that the MEA using the lead dioxide fine mesh electrode as anode and a fine mesh stainless steel electrode as cathode, pressed against the SPE, is stable for the ozone production.