Alternative electrolytes, such as citrate baths, are now studied, aiming to reduce the toxicity and the cost of the electroplating process while maintaining the decorative qualities and anticorrosive properties of the coatings. For this purpose, brightening and/or leveling compounds are usually added to the base citrate bath. In this work, Cu-Zn alloys were electroplated on mild steel substrates from electrolytes containing sodium citrate and additives (benzotriazole and cysteine) at constant stirring speed. The results showed that coatings produced from baths containing additives were brighter than those obtained from the base citrate bath. Additionally, the presence of benzotriazole directly influenced the coating composition and the properties of the deposited alloy: the amount of zinc in this coating increased excessively, and the coating/substrate corrosion presented a poor anticorrosive performance.