CATALYTIC PROPERTIES OF PARTIALLY REDUCED COBALT WIRE IN CO HYDROGENATION

Shin HK; Nam IS; Lee JS; Chung JS; Moon SH

Korean Journal of Chemical Engineering, Vol.13, No.1, 54-59, January, 1996

Shin HK, Nam IS, Lee JS, Chung JS, Moon SH

The reaction rate and the ethylene/ethane product ratio in CO hydrogenation increase when cobalt wire, used as a catalyst for the reaction, is reduced to lower extents. The kinetic results obtained with the poorly reduced wire correlate well with temperature-programmed surface reaction(TPSR) and H₂ chemisorption results, and are interpreted to be due to electronic modification of the cobalt surface by the unreduced sub-surface cobalt oxide. It has been concluded that the extent of metal reduction is an important variable in determining the catalytic property of cobalt.

[References]

Amelse JA, Schwartz LH, Butt JB, J. Catal., 72, 95 (1981)
Bartholomew CH, Farrauto RJ, J. Catal., 45, 41 (1976)
Boudart M, Adv. Catal., 20, 153 (1969)
Dwyer DJ, Somorjai GA, J. Catal., 52, 291 (1978)
Fu L, Bartholomew CH, J. Catal., 92, 376 (1985)
Ignatiev A, Matsuyama T, J. Catal., 58, 328 (1979)
Johnson BG, Bartholomew CH, Goodman DW, J. Catal., 128, 231 (1991)
Lee WH, Bartholomew CH, J. Catal., 120, 256 (1989)
Lee JH, Lee DK, Ihm SK, J. Catal., 113, 544 (1988)
McCarty JG, Wise H, J. Catal., 57, 406 (1979)
Moon SH, Park CW, Shin HK, "New Frontiers in Catalysis (Guczi. L et al.)," 2757, Akademiai Kiado, Budapest (1993)
Moon SH, Yoon KE, Appl. Catal., 16, 289 (1985)
Moon SH, Yoon KE, Kim YG, Korean J. Chem. Eng., 3(1), 61 (1986)
Paal Z, Menon PG, "Hydrogen Effects in Catalysis," p. 543 Marcel Dekker, Inc., New York, NY (1988)
Palmer RL, Vroom DA, J. Catal., 50, 244 (1977)
Reuel RC, Bartholomew CH, J. Catal., 85, 78 (1984)
van Hardeveld R, Hartog F, Adv. Catal., 22, 75 (1972)
Smith CE, Biberian JP, Somorjai GA, J. Catal., 57, 426 (1979)
Vannice MA, J. Catal., 50, 228 (1977)

[Referenced By]

[1] Amelse JA, Schwartz LH, Butt JB, J. Catal., 72, 95 (1981)

[2] Bartholomew CH, Farrauto RJ, J. Catal., 45, 41 (1976)

[3] Boudart M, Adv. Catal., 20, 153 (1969)

[4] Dwyer DJ, Somorjai GA, J. Catal., 52, 291 (1978)

[5] Fu L, Bartholomew CH, J. Catal., 92, 376 (1985)

[6] Ignatiev A, Matsuyama T, J. Catal., 58, 328 (1979)

[7] Johnson BG, Bartholomew CH, Goodman DW, J. Catal., 128, 231 (1991)

[8] Lee WH, Bartholomew CH, J. Catal., 120, 256 (1989)

[9] Lee JH, Lee DK, Ihm SK, J. Catal., 113, 544 (1988)

[10] McCarty JG, Wise H, J. Catal., 57, 406 (1979)

[11] Moon SH, Park CW, Shin HK, "New Frontiers in Catalysis (Guczi. L et al.)," 2757, Akademiai Kiado, Budapest (1993)

[12] Moon SH, Yoon KE, Appl. Catal., 16, 289 (1985)

[13] Moon SH, Yoon KE, Kim YG, Korean J. Chem. Eng., 3(1), 61 (1986)

[14] Paal Z, Menon PG, "Hydrogen Effects in Catalysis," p. 543 Marcel Dekker, Inc., New York, NY (1988)

[15] Palmer RL, Vroom DA, J. Catal., 50, 244 (1977)

[16] Reuel RC, Bartholomew CH, J. Catal., 85, 78 (1984)

[17] van Hardeveld R, Hartog F, Adv. Catal., 22, 75 (1972)

[18] Smith CE, Biberian JP, Somorjai GA, J. Catal., 57, 426 (1979)

[19] Vannice MA, J. Catal., 50, 228 (1977)