A new triply bridged binuclear manganese(III) complex, [Mn(III)2(mu-O(mu-O2CCH3)2-(MeL)2](PF6)2.H2O[MeL = (2-pyridylethyl)(2-pyridylmethyl)methylamine], has been synthesized using MeL as a facially capping tridentate amine/pyridine ligand. The complex has been isolated as a purplish brown solid, which has been characterized by spectroscopic and cyclic voltammetric techniques. Two redox be transformations have been neatly identified from this study : [GRAPHICS]