Preparation of hydrophobic self-assembled monolayers on paper surface with silanes

Min-Jung Oh; Sun-Young Lee; Ki-Hyon Paik

Journal of Industrial and Engineering Chemistry, Vol.17, No.1, 149-153, January, 2011

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Preparation of hydrophobic self-assembled monolayers on paper surface with silanes

Min-Jung Oh, Sun-Young Lee¹, and Ki-Hyon Paik^†

Division of Environmental Science and Ecological Engineering, College of Life Sciences and Biotechnology, Korea University, Seoul 136-701, Republic of Korea
¹Department of Forest Resources Utilization, Korea Forest Research Institute, Seoul 130-712, Republic of Korea

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This study was conducted to obtain hydrophobic self-assembled monolayers on paper surface with silanes by a simple and facile method in the vapor or solvent phase. Filter papers with water contact angle over 120 ℃ were successfully prepared under sufficient reaction time and silane concentration, and their hydrophobic properties were evaluated by the contact angle measurement and stockigt size test. And the effect of SAM-formation on mechanical properties of paper like wet tensile strength and PPS roughness was also presented. Results from the study reveal the effective reaction time and silane concentration to form stable SAM depending on the coating method and the silane treatments. The fabrication of self-assembled monolayers on the surface of the papers with silanes proved to be a simple process for the preparation of the superhydrophobic papers.

Keywords:Self-assembled monolayer (SAM);Hydrophobic;Silanes;Water contact angle (WCA)

[References]

Gary AS, Handbook for Pulp & Paper Technologists, 3rd ed., Angus Wilde Publications, Vancouver-Bellingham, p. 221. (2004)
Ulman A, Chem. Rev., 96(4), 1533 (1996)
Kim JY, Park YH, Kim JS, Lim KT, Jeong YT, J. Ind. Eng. Chem., 13(6), 1023 (2007)
Yeh JM, Chang KC, J. Ind. Eng. Chem., 14(3), 275 (2008)
Artus GRJ, Jung S, Zimmermann J, Gautschi HP, Marquardt K, Seeger S, Adv. Mater., 18(20), 2758 (2006)
Zimmermann J, Reifler FA, Fortunato G, Gerhardt LC, Seeger S, Adv. Funct. Mater., 18(22), 3662 (2008)
Li S, Xie H, Zhang S, Wang X, Chem. Commun., 46, 4857 (2007)
Li SH, Zhang SB, Wang XH, Langmuir, 24(10), 5585 (2008)
Linford MR, Fenter P, Eisenberger PM, Chidsey CE, J. Am. Chem. Soc., 117(11), 3145 (1995)
Park SY, J. Ind. Eng. Chem., 16(4), 560 (2010)
Shang HM, Wang Y, Limmer SJ, Chou TP, Takahashi K, Cao GZ, Thin Solid Films, 472(1-2), 37 (2005)
Fadeev AY, McCarthy TJ, Langmuir., 15(9), 375 (1999)
Abdelmouleh M, Boufi S, Belgacem MN, Duarte AP, Ben Salah A, Gandini A, J. Adhes. Adhesives., 24, 43 (2004)
Bubois LA, Zegarski BR, Nuzzo RG, J. Am. Chem. Soc., 112, 570 (1990)
Hare EF, Shafrin EG, Zisman WA, J. Phys. Chem., 58, 236 (1954)
Banga R, Yarwood J, Morgan AM, Evans B, Kells J, Langmuir, 11(11), 4393 (1995)
Wasserman SR, Tao YT, Whitesides JM, Langmuir., 5, 1074 (1989)
Kawasaki M, Sato T, Tanaka T, Takao K, Langmuir, 16(4), 1719 (2000)
Tripp CT, Hair ML, Langumuir., 8, 1120 (1992)
Mathais T, Brent SM, Kasenya G, Franz G, J. Colloid Interface Sci., 148, 182 (1992)
Allara DL, Parikh AN, Rondelez F, Langmuir, 11(7), 2357 (1995)
Brzoska JB, Benazouz I, Rondelez F, Langmuir, 10(11), 4367 (1994)
Yamada R, Wano H, Uosaki K, Langmuir, 16(13), 5523 (2000)
Tappi Press, Tappi Test Method T458 om-84, T555 om-99, Atlanta, USA (1999)
Korea Standard Association, KS M 7025, KS M ISO 3781 (2007)
Love JC, Wolfe DB, Haasch R, Chabinyc ML, Paul KE, Whitesides GM, Nuzzo RG, J. Am. Chem. Soc., 125(9), 2597 (2003)
Silberzan P, Le´ ger L, Ausserre´ D , Benattar JJ, Langmuir., 7, 1647 (1991)

[Referenced By]

[1] Gary AS, Handbook for Pulp & Paper Technologists, 3rd ed., Angus Wilde Publications, Vancouver-Bellingham, p. 221. (2004)

[2] Ulman A, Chem. Rev., 96(4), 1533 (1996)

[3] Kim JY, Park YH, Kim JS, Lim KT, Jeong YT, J. Ind. Eng. Chem., 13(6), 1023 (2007)

[4] Yeh JM, Chang KC, J. Ind. Eng. Chem., 14(3), 275 (2008)

[5] Artus GRJ, Jung S, Zimmermann J, Gautschi HP, Marquardt K, Seeger S, Adv. Mater., 18(20), 2758 (2006)

[6] Zimmermann J, Reifler FA, Fortunato G, Gerhardt LC, Seeger S, Adv. Funct. Mater., 18(22), 3662 (2008)

[7] Li S, Xie H, Zhang S, Wang X, Chem. Commun., 46, 4857 (2007)

[8] Li SH, Zhang SB, Wang XH, Langmuir, 24(10), 5585 (2008)

[9] Linford MR, Fenter P, Eisenberger PM, Chidsey CE, J. Am. Chem. Soc., 117(11), 3145 (1995)

[10] Park SY, J. Ind. Eng. Chem., 16(4), 560 (2010)

[11] Shang HM, Wang Y, Limmer SJ, Chou TP, Takahashi K, Cao GZ, Thin Solid Films, 472(1-2), 37 (2005)

[12] Fadeev AY, McCarthy TJ, Langmuir., 15(9), 375 (1999)

[13] Abdelmouleh M, Boufi S, Belgacem MN, Duarte AP, Ben Salah A, Gandini A, J. Adhes. Adhesives., 24, 43 (2004)

[14] Bubois LA, Zegarski BR, Nuzzo RG, J. Am. Chem. Soc., 112, 570 (1990)

[15] Hare EF, Shafrin EG, Zisman WA, J. Phys. Chem., 58, 236 (1954)

[16] Banga R, Yarwood J, Morgan AM, Evans B, Kells J, Langmuir, 11(11), 4393 (1995)

[17] Wasserman SR, Tao YT, Whitesides JM, Langmuir., 5, 1074 (1989)

[18] Kawasaki M, Sato T, Tanaka T, Takao K, Langmuir, 16(4), 1719 (2000)

[19] Tripp CT, Hair ML, Langumuir., 8, 1120 (1992)

[20] Mathais T, Brent SM, Kasenya G, Franz G, J. Colloid Interface Sci., 148, 182 (1992)

[21] Allara DL, Parikh AN, Rondelez F, Langmuir, 11(7), 2357 (1995)

[22] Brzoska JB, Benazouz I, Rondelez F, Langmuir, 10(11), 4367 (1994)

[23] Yamada R, Wano H, Uosaki K, Langmuir, 16(13), 5523 (2000)

[24] Tappi Press, Tappi Test Method T458 om-84, T555 om-99, Atlanta, USA (1999)

[25] Korea Standard Association, KS M 7025, KS M ISO 3781 (2007)

[26] Love JC, Wolfe DB, Haasch R, Chabinyc ML, Paul KE, Whitesides GM, Nuzzo RG, J. Am. Chem. Soc., 125(9), 2597 (2003)

[27] Silberzan P, Le´ ger L, Ausserre´ D , Benattar JJ, Langmuir., 7, 1647 (1991)