This study demonstrates the course of solubility and (liquid + liquid) equilibrium (LLE) for the system (cyclohexane + 1-butanol + 2,2,2-trifluoroethanol) at temperatures of (288.15, 298.15, and 308.15) K and pressure 101.3 kPa. The titration method was used to assess solubility (binodal) curves, while a direct analytical method to acquire tie lines. The consistency of the binodal curves and phase diagrams data were well calculated by Hand and Othmer-Tobias empirical equations. The NRTL and UNIQUAC thermodynamic models gave accurate tie-line values for the systems. Plait-point, distribution coefficient, solvent selectivity, and NRTL and UNIQUAC binary interaction parameters were obtained. The immiscibility region of the system decreases significantly with increasing temperature. The results present an overview of the high efficiency of liquid extraction using 2,22-trifluoroethanol as solvent to yield pure cyclohexane from its 1-butanol azeotrope mixture at ambient temperatures. (C) 2010 Elsevier Ltd. All rights reserved.