POLYMERIZATION OF PROPYLENE OVER SOLVAY/Cp<SUB>2</SUB>TiMe<SUB>2</SUB> CATALYST

Yoon JS; Oh JK; Hong KP; Lee IM

Korean Journal of Chemical Engineering, Vol.13, No.2, 207-210, March, 1996

POLYMERIZATION OF PROPYLENE OVER SOLVAY/Cp₂TiMe₂ CATALYST

Propylene polymerization behavior of a highly isospecific catalyst, Solvay/Cp₂TiMe₂, was investigated. Polypropylene from the Solvay/Cp₂TiMe₂ system showed higher I.I% with less dependence on reaction temperature than that produced from the Solvay/DEAC system.

Keywords:Propylene Polymerization;Solvay Catalystm Cp₂TiMe₂;Isotacticity;Morphology

[References]

Clauss K, Bestian H, Justus Liebigs Ann. Chem., 654, 8 (1962)
Soga K, Lee DH, Yanagihara H, Polym. Bull., 20, 237 (1988)
Soga K, Yanagihara H, Macromolecules, 22(7), 2875 (1989)
Soga K, Yanagihara H, Makromol. Chem., 189, 2839 (1988)
Soga K, Uozumi T, Park JR, Makromol. Chem., 191, 2853 (1990)
Sun L, Soga K, Makromol. Chem., 190(12), 3137 (1989)

[Referenced By]

[1] Clauss K, Bestian H, Justus Liebigs Ann. Chem., 654, 8 (1962)

[2] Soga K, Lee DH, Yanagihara H, Polym. Bull., 20, 237 (1988)

[3] Soga K, Yanagihara H, Macromolecules, 22(7), 2875 (1989)

[4] Soga K, Yanagihara H, Makromol. Chem., 189, 2839 (1988)

[5] Soga K, Uozumi T, Park JR, Makromol. Chem., 191, 2853 (1990)

[6] Sun L, Soga K, Makromol. Chem., 190(12), 3137 (1989)