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Journal of Crystal Growth, Vol.316, No.1, 1-5, 2011
Effects of chlorine drag on the annealing-induced abnormal grain growth in polycrystalline CdTe
The annealing of chlorine-doped polycrystalline CdTe films results in the formation of large secondary grains within a smaller primary grain matrix. Growth kinetics is driven by chlorine drag for both types of grains and modeled within Burke's approach. The activation energy for grain boundary motion is 1.65 +/- 0.1 eV, corresponding to the activation energy for chlorine diffusion in CdTe and revealing the occurrence of a diffusion-induced grain boundary migration. The < 1 00 > texture is enhanced by secondary grain growth but subsequently lessened by the thickening of annealing twins in their center. (C) 2010 Elsevier B.V. All rights reserved.
Keywords:Thermal annealing;Recrystallization;Growth models;Physical vapor deposition processes;Semiconducting: II-VI materials