Evaluations of vacuum brazed commercially pure titanium and low-carbon steel joints using one copper-based alloy (Cu-12Mn-2Ni) and two silver-based braze alloys (Ag-34Cu-2Ti, Ag-27.25Cu-12.5In-1.25Ti) have been studied. Both the interfacial microstructures and mechanical properties of brazed joints were investigated to evaluate the joint quality. The optical and scanning electron microscopic results showed that all the filler metals interact metallurgically with steel and titanium, forming different kinds of intermetallic compounds (IMC) such as CuTi, Cu2Ti, Cu4Ti3, and FeTi. The presence of IMC (interfacial reaction layers) at the interfacial regions strongly affects the shear strength of the joints. Furthermore, it was found that the shear strength of brazed joints and the fracture path strongly depend on the thickness of the IMC. The maximum shear strength of the joints was 113 MPa for the specimen brazed at 750 A degrees C using an Ag-27.25Cu-12.5In-1.25Ti filler alloy.