Phosphate glasses containing tin and tungsten oxides were produced by microwave heating under a nitrogen protective atmosphere. Microwaves permit to heat the raw materials at temperatures close to 1000 A degrees C in short time and to obtain homogeneous glasses in less than 10 min. All samples were characterized from thermal and mechanical point of view as function of metal oxide proportions. The equimolar addition of SnO and WO3 in sodium phosphate matrix involves a linear evolution of the different properties (T (g), CTE, density, mechanical properties, and durability). Thus, we have shown a progressive strengthening of the network. The glass transition temperature does not exceed 405 A degrees C, and the chemical durability is improved to four orders of magnitude. The dissolution rate is equal to 3.4 x 10(-7) g cm(-2) min(-1) for 40NaPO(3)-30SnO-30WO(3) glass composition and is comparable with those of the window glass.