We have prepared four light-emitting polymers bearing a chromophore composed of carbazole and fluorene by the Suzuki coupling polycondensation. Two nonconjugated polymers (P3CzBFXy and P2CzFXy) had a chromophore tethered by the p-xylylene spacer, whose connection point between carbazole and fluorene in addition to the number of fluorene unit was systematically changed to investigate the emission wavelength and intensity. The red-shifted absorption and emission maximum wavelengths together with the improved fluorescence quantum yield of polymers P3CzBFXy and P2CzFXy indicate that the increment of the number of para-connected benzene rings included in the chromophore effectively extends the conjugation length. The fact that polymer P3CzBFXy has longer wavelength absorption and emission spectra also indicates the interaction of the carbazole nitrogen lone pair with the oligophenylene moiety. Other two polymers P3CzFPy and P3CzFPym having the heterocycle directly bound to the carbazole nitrogen were prepared to know the character of the carbazole nitrogen lone pair and their influence on the fluorescence behavior. The fluorescence spectra of polymer P3CzFPym bearing the pyrimidine ring gradually red-shifted in conjunction with the decrease of fluorescence quantum yield on going from toluene solution to CHCl3 solution because of the intramolecular charge transfer at the excited state. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3729-3735, 2010