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Journal of Power Sources, Vol.196, No.1, 596-599, 2011
Panchromatic response composed of hybrid visible-light absorbing polymers and near-IR absorbing dyes for nanocrystalline TiO2-based solid-state solar cells
In pursuit of panchromatic sensitizers for mesoporous TiO2-based solid-state solar cells, a near-IR absorbing zinc phthalocyanine dye (coded TT1) was firstly adsorbed over relatively thin (similar to 1 mu m) TiO2 mesoporous films and then a visible-light absorbing polymer [regioregular poly(3-hexylthiophene). P3HT] was incorporated into the mesopores as both a second sensitizer and a solid hole conductor. After optimizing some experimental parameters, these hybrid solid-state cells exhibited a clear panchromatic response, and an overall conversion efficiency of around 1% at full sun intensity. (C) 2010 Elsevier B.V. All rights reserved.
Keywords:Hybrid sensitizer;Dye-sensitized solar cell (DSSC);Poly(3-hexylthiophene);Zinc phthalocyanine dye (TT1);Solid-state solar cell