A series of multi-block poly(arylene ether sulfone)s are synthesized via the copolymerization of bis(4-hydroxyphenol) sulfone, 3,3', 5,5'-tetramethylbiphenol and 4,4'-difluorodiphenyl sulfone. The resulting multi-block copolymers are brominated by using N-bromosuccinmide (NBS) as bromination reagent. The bromomethylated copolymer is solution cast to form clear, creasable films, and subsequent soaking of these films in aqueous trimethylamine to give benzyltrimethylammonium groups. The anion exchange membranes obtained by the solution hydroxide exchange with aqueous sodium hydroxide show varying degrees of ionic conductivity depending on their ion exchange capacity. The highest hydroxide conductivity 0.029 S cm(-1) is achieved with the QBPES-40 membrane having IEC value of 1.62 mequiv g(-1) at room temperature and 100% RH. The obtained anion exchange membranes also have good mechanical properties and dimensional stability, which greatly facilitates the preparation of a MEA and the cell operation. (C) 2011 Elsevier B.V. All rights reserved.