2D Polymeric Silver(I) Complexes Consisting of Markedly Undulated Sheets of Squares - X-Ray Crystal-Structures of (Ag(Ppz)(2))(BF4) and (Ag(Pyz)(2))(PF6) (Ppz=piperazine, Pyz=pyrazine)

Carlucci L; Ciani G; Proserpio DM; Sironi A

Inorganic Chemistry, Vol.34, No.22, 5698-5700, 1995

Carlucci L, Ciani G, Proserpio DM, Sironi A

Two novel silver(I) coordination polymers, [Ag(ppz)(2)](BF4) (1) and [Ag(pyz)(2)](PF6) (2) (ppz = piperazine, pyz = pyrazine), are prepared. Their crystal structures are found to contain markedly undulated 2D networks of distorted squares of Ag+ cations, in tetrahedral (1) and disphenoidal coordination geometries (2).

Keywords:DIAMOND STRUCTURE;CONDUCTIVITY;FRAMEWORKS