Inorganic Chemistry, Vol.34, No.25, 6239-6240, 1995
Facile Abstraction of Successive Oxygen-Atoms from Perchlorate Ions by Methylrhenium Dioxide
Methylrhenium dioxide, CH1ReO2, reduces perchlorate and chlorate ions by oxygen-atom abstraction at record-high rates, > 10(2,4) times more rapidly than any other values reported for these anions.
Keywords:MAIN-GROUP ELEMENTS;TRANSITION-METALS;MULTIPLE BONDS;HYDROGEN-PEROXIDE;METHYLTRIOXORHENIUM;OXIDATION;KINETICS;RHENIUM;OXIDES