MEASUREMENT OF VAPOR SORPTION EQUILIBRIA OF POLYMER SOLUTIONS AND COMPARATIVE CORRELATION BY G<SUP>E</SUP>-MODELS AND LATTICE EQUATIONS OF STATE

Kim J; Joung KC; Hwang S; Huh W; Lee CS; Yoo KP

Korean Journal of Chemical Engineering, Vol.15, No.2, 199-210, March, 1998

MEASUREMENT OF VAPOR SORPTION EQUILIBRIA OF POLYMER SOLUTIONS AND COMPARATIVE CORRELATION BY G^E-MODELS AND LATTICE EQUATIONS OF STATE

Kim J, Joung KC, Hwang S, Huh W, Lee CS, Yoo KP

Solvent sorption equilibrium data of binary solvent-polymer systems were measured with a vacuum electro-microbalance equilibrium cell. Tested solvents were benzene, n-pentane, cyclohexane, n-hexane, water and methanol. Polymers tested were poly(dimethylsiloxane), poly(iso-butylene), poly(propylene oxide) and poly(vinyl alcohol). Data obtained in the present study, together with existing literature data, were correlated by two g^E-models, such as UNIQUAC and the Flory-Huggins model, and four equations of state which stem from the lattice fluid theory, such as models proposed by Flory, Sanchez and Lacombe, Panayiotou and Vera, and the NLF model proposed recently by the present authors. For each solvent-polymer system, the provided models give a quantitative correlation. The advantages and drawbacks of the g^E-model and equation of state approaches are also discussed.

Keywords:Experimental Method;Vapor Sorption Equilibria;Polymer Solutions;g^E-Model;Lattice Equations of State

[References]

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Ashworth AJ, Chien CF, Furio DL, Hooker D, Kopecnk MM, Laub RJ, Price GJ, Macromolecules, 17, 1090 (1984)
Baker RW, Yoshioka N, Mohr JM, Kahn AJ, J. Membr. Sci., 31, 259 (1987)
Ballatine DS, Wohltjen H, Anal. Chem., 61, 704A (1989)
Bawn CEH, Patel RD, Trans. Faraday Soc., 52, 1664 (1956)
Beret S, Prausnitz JM, Macromolecules, 8, 535 (1975)
Beret S, Prausnitz JM, AIChE J., 21, 1123 (1975)
Booth WB, Devoy CJ, Polymer, 12, 320 (1971)
Danner RP, High MS, "Handbook of Polymer Solution Thermodynamics," DIPPR, AIChE Press, New York (1993)
Eichinger BE, Flory PJ, Macromolecules, 1, 285 (1968)
Eichinger BE, Flory PJ, Trans. Faraday Soc., 64, 2061 (1968)
Flory PJ, J. Chem. Phys., 9, 660 (1941)
Flory PJ, J. Chem. Phys., 10, 51 (1942)
Flory PJ, Daoust H, J. Polym. Sci., 25 (1957)
Flory PJ, Disc. Faraday Soc., 49, 7 (1970)
Grate JW, Klusty M, McGill RA, Abraham MH, Whiting G, Andonian-Haftvan J, Anal. Chem., 64, 610 (1992)
Guggenheim EA, "Mixtures," Clarendon Press, Oxford (1952)
Huang SH, Radosz M, Ind. Eng. Chem. Res., 30, 1994 (1991)
Huggins ML, J. Chem. Phys., 9, 440 (1941)
Huggins ML, J. Phys. Chem., 46, 51 (1942)
Kershaw RW, Malcolm GN, Trans. Faraday Soc., 64, 323 (1968)
Lakhanpal ML, Conway BE, J. Polym. Sci., 46, 75 (1960)
Lee CS, Yoo KP, "Lattice-Hole Based Equations of State and Their Applications to Complex Fluids," Proc. Int. Symp. on Molec. Thermo. and Molec. Simul., 12-15 January, 109, 53 (1997)
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Lucchelli E, Tomka I, Vancso G, Yeh PL, Polym. Bull., 20, 569 (1988)
Maeda Y, Tsuyumoto M, Karakane H, Tsugaya H, Polym. J., 23, 501 (1991)
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McGlashan JM, Wormald CJ, Trans. Faraday Soc., 60, 646 (1964)
McKinney JE, Goldstein MJ, Res. Nati'l Ber. Stand. A, 78, 331 (1974)
Napper DH, "Polymeric Stabilization of Colloidal Dispersions," London, Academic Press, Inc. (1983)
Panayiotou C, Vera JH, Fluid Phase Equilib., 5, 55 (1980)
Panayiotou C, Vera JH, Can. J. Chem. Eng., 59, 501 (1981)
Panayiotou C, Vera JH, Polym. J., 14, 681 (1982)
Reid RC, Prausnitz JM, Poling PE, "The Properties of Gases and Liquids," 3rd Ed., McGraw-Hill, New York (1987)
Sakurada I, Nakajima A, Fujiwara H, J. Polym. Sci., 35, 497 (1959)
Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2352 (1976)
Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2568 (1976)
Sanchez IC, Lacombe RH, Macromolecules, 11, 1145 (1978)
Smith JM, Van Ness HC, "Chemical Engineering Series 4th," McGraw-Hill Company, 573 (1987)
Sugamiya K, Kuwhara N, Kaneko I, Macromolecules, 7, 66 (1974)
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You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)
Yoo KP, Kim H, Lee CS, Korean J. Chem. Eng., 12(3), 277 (1995)
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Yoo KP, Kim J, Kim H, You SS, Lee CS, J. Chem. Eng. Jpn., 29(3), 439 (1996)

[Referenced By]

[1] Abrams DC, Prausnitz JM, AIChE J., 21, 116 (1975)

[2] Ashworth AJ, Chien CF, Furio DL, Hooker D, Kopecnk MM, Laub RJ, Price GJ, Macromolecules, 17, 1090 (1984)

[3] Baker RW, Yoshioka N, Mohr JM, Kahn AJ, J. Membr. Sci., 31, 259 (1987)

[4] Ballatine DS, Wohltjen H, Anal. Chem., 61, 704A (1989)

[5] Bawn CEH, Patel RD, Trans. Faraday Soc., 52, 1664 (1956)

[6] Beret S, Prausnitz JM, Macromolecules, 8, 535 (1975)

[7] Beret S, Prausnitz JM, AIChE J., 21, 1123 (1975)

[8] Booth WB, Devoy CJ, Polymer, 12, 320 (1971)

[9] Danner RP, High MS, "Handbook of Polymer Solution Thermodynamics," DIPPR, AIChE Press, New York (1993)

[10] Eichinger BE, Flory PJ, Macromolecules, 1, 285 (1968)

[11] Eichinger BE, Flory PJ, Trans. Faraday Soc., 64, 2061 (1968)

[12] Flory PJ, J. Chem. Phys., 9, 660 (1941)

[13] Flory PJ, J. Chem. Phys., 10, 51 (1942)

[14] Flory PJ, Daoust H, J. Polym. Sci., 25 (1957)

[15] Flory PJ, Disc. Faraday Soc., 49, 7 (1970)

[16] Grate JW, Klusty M, McGill RA, Abraham MH, Whiting G, Andonian-Haftvan J, Anal. Chem., 64, 610 (1992)

[17] Guggenheim EA, "Mixtures," Clarendon Press, Oxford (1952)

[18] Huang SH, Radosz M, Ind. Eng. Chem. Res., 30, 1994 (1991)

[19] Huggins ML, J. Chem. Phys., 9, 440 (1941)

[20] Huggins ML, J. Phys. Chem., 46, 51 (1942)

[21] Kershaw RW, Malcolm GN, Trans. Faraday Soc., 64, 323 (1968)

[22] Lakhanpal ML, Conway BE, J. Polym. Sci., 46, 75 (1960)

[23] Lee CS, Yoo KP, "Lattice-Hole Based Equations of State and Their Applications to Complex Fluids," Proc. Int. Symp. on Molec. Thermo. and Molec. Simul., 12-15 January, 109, 53 (1997)

[24] Lichtenthaler RN, Liu DD, Prausnitz JM, Macromolecules, 11, 192 (1978)

[25] Lucchelli E, Tomka I, Vancso G, Yeh PL, Polym. Bull., 20, 569 (1988)

[26] Maeda Y, Tsuyumoto M, Karakane H, Tsugaya H, Polym. J., 23, 501 (1991)

[27] Matsumoto K, Ishii K, Kuroda T, Inoue K, Iwama A, Polym. J., 23, 491 (1991)

[28] McGlashan JM, Wormald CJ, Trans. Faraday Soc., 60, 646 (1964)

[29] McKinney JE, Goldstein MJ, Res. Nati'l Ber. Stand. A, 78, 331 (1974)

[30] Napper DH, "Polymeric Stabilization of Colloidal Dispersions," London, Academic Press, Inc. (1983)

[31] Panayiotou C, Vera JH, Fluid Phase Equilib., 5, 55 (1980)

[32] Panayiotou C, Vera JH, Can. J. Chem. Eng., 59, 501 (1981)

[33] Panayiotou C, Vera JH, Polym. J., 14, 681 (1982)

[34] Reid RC, Prausnitz JM, Poling PE, "The Properties of Gases and Liquids," 3rd Ed., McGraw-Hill, New York (1987)

[35] Sakurada I, Nakajima A, Fujiwara H, J. Polym. Sci., 35, 497 (1959)

[36] Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2352 (1976)

[37] Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2568 (1976)

[38] Sanchez IC, Lacombe RH, Macromolecules, 11, 1145 (1978)

[39] Smith JM, Van Ness HC, "Chemical Engineering Series 4th," McGraw-Hill Company, 573 (1987)

[40] Sugamiya K, Kuwhara N, Kaneko I, Macromolecules, 7, 66 (1974)

[41] Timmermans J, "Physico-Chemical Constants of Pure Organic Compounds," Elsevier, New York, Vol. 1. (1965)

[42] Timmermans J, "Physico-Chemical Constants of Pure Organic Compounds," Elsevier, New York, Vol. II (1965)

[43] You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)

[44] You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)

[45] Yoo KP, Kim H, Lee CS, Korean J. Chem. Eng., 12(3), 277 (1995)

[46] Yoo KP, Kim H, Lee CS, Korean J. Chem. Eng., 12(3), 289 (1995)

[47] Yoo KP, Kim J, Kim H, You SS, Lee CS, J. Chem. Eng. Jpn., 29(3), 439 (1996)