화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.28, No.6, 1393-1399, June, 2011
DOI10.1007/s11814-011-0092-7  Export Citation
Perchlorate removal in aqueous solutions using periodic mesoporous organosilicas (PMOs) functionalized with quaternary ammonium groups
Sang Don Lee, Byunghwan Lee†, and Kwang-Ho Choo1
  • Department of Chemical System Engineering, Keimyung University, 2800 Dalgubeoldaero, Dalseo-gu, Daegu 704-701, Korea
  • 1Department of Environmental Engineering, Kyungpook National University, 1370 Sankyeok-dong, Buk-gu, Daegu 702-701, Korea
E-mail:
Perchlorate anion (ClO^(-)4.) in water has become an environmental issue of concern because it can impair proper functioning of the thyroid gland. For the removal of perchlorate anions from water, adsorption using anionexchange resins has been generally used as the most suitable method. In this work, we prepared periodic mesoporous organosilica materials (PMOs) functionalized with quaternary ammonium ligands, and used them for the removal of perchlorate anions from aqueous solutions. The physical and chemical properties of prepared samples were measured using nitrogen adsorption-desorption measurement, elemental analyses, X-ray diffractometer, and infrared spectrometer. We also investigated equilibrium isotherms for the measurement of adsorption capacities and kinetic performance of the prepared samples.
Keywords:Perchlorate;Periodic Mesoporous Organosilica Materials (PMOs);Quaternary Ammonium Ligands;Anionexchange Resin
  1. Bull RJ, Chang AC, Cranor CF, Shank RC, Trussell R, Perchlorate in drinking water: A science and policy review, Urban Water Research Center, University of California, Irvine, CA (2004)
  2. Brown GM, Gu B, in Perchlorate: Environmental occurrence, interactions and treatment, B. Gu and J. D. Coates Eds., Springer, New York (2006)
  3. Yonhap News, July 28 (2006)
  4. Logan BE, Environ. Sci. Technol., 35, 482A (2001)
  5. Xiong Z, Zhao D, Harper WF, Ind. Eng. Chem. Res., 46(26), 9213 (2007)
  6. Hristovski K, Westerhoff P, Moller T, Sylvester P, Condit W, Mash H, J. Hazard. Mater., 152(1), 397 (2008)
  7. Yoon IH, Meng XG, Wang C, Kim KW, Bang S, Choe E, Lippincott L, J. Hazard. Mater., 164(1), 87 (2009)
  8. Gu B, Ku YK, Brown GM, Federal Facilities Environ. J., Spring, 75 (2003)
  9. Gu B, Ku YK, Brown GM, Environ. Sci. Technol., 39, 901 (2005)
  10. Gu B, Brown GM, Chiang CC, Gu, Y.-K. Ku and G. M. Brown., 41, 6277 (2007)
  11. Ju YH, Webb OF, Dai S, Lin JS, Barnes CE, Ind. Eng. Chem. Res., 39(2), 550 (2000)
  12. Lee B, Bao LL, Im HJ, Dai S, Hagaman EW, Lin JS, Langmuir, 19(10), 4246 (2003)
  13. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)
  14. Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
  15. Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
  16. Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 14, 4603 (2002)
  17. Fryxell GE, Liu J, Hauser TA, Nie Z, Ferris KF, Mattigod S, Gong M, Hallen RT, Chem. Mater., 11, 2148 (1999)
  18. Lin Y, Fryxell GE, Wu H, Engelhard M, Environ. Sci. Technol., 35, 3962 (2001)
  19. Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 15, 1713 (2003)
  20. Jang M, Shin EW, Park JK, Choi SI, Environ. Sci. Technol., 37, 5062 (2003)
  21. Shin EW, Han JS, Jang M, Min SH, Park JK, Rowell RM, Environ. Sci. Technol., 38, 912 (2004)
  22. Kim Y, Kim C, Choi I, Rengaraj S, Yi J, Environ. Sci. Technol., 38, 924 (2004)
  23. Kim TH, Jang M, Park JK, Micropor. Mesopor. Mater., 108, 22 (2008)
  24. Lee B, Chung YS, Park C, Korean Chem. Eng. Res., 46(2), 436 (2008)
  25. Chung YS, Lee B, Choo KH, Choi SJ, J. Ind. Eng. Chem., 17(1), 114 (2011)
  26. Inagaki S, Guan S, Ohsuna T, Terasaki O, Nature., 416, 304 (2002)
  27. Goto Y, Inagaki S, Chem. Commun., 2410 (2002)
  28. Burleigh MC, Markowitz MA, Spector MS, Gaber BP, Environ. Sci. Technol., 36, 2515 (2002)
  29. Barr ME, Jarvinen GD, Moody EW, Vaughn R, Silks LA, Bartsch RA, Sep. Sci. Technol., 37(5), 1065 (2002)
  30. Lee B, Im HJ, Luo HM, Hagaman EW, Dai S, Langmuir, 21(12), 5372 (2005)
  31. Qiao SZ, Yu CZ, Hu QH, Jin YG, Zhou XF, Zhao XS, Lu GQ, Micropor. Mesopor. Mater., 91, 59 (2006)
  32. Kim YH, Lee B, Choo KH, Choi SJ, Micropor. Mesopor. Mater., 138, 184 (2011)
  33. Hao N, Wang H, Webley PA, Zhao D, Micropor. Mesopor. Mater., 132, 543 (2010)
  34. Burkett SL, Sims SD, Mann S, Chem. Commun., 1367 (1996)
  35. Socrates G, Infrared and raman characteristic group frequencies, 3rd Ed., Wiley, Chichester (2001)
  36. Kim Y, Lee B, Cho YS, Yi J, Korean Chem. Eng. Res., 39, 228 (2001)
  37. Choi HS, Lee DG, Cho GJ, Lee CY, Chung JS, Yoo IK, Shin EW, Korean Chem. Eng. Res., 44(2), 172 (2006)
  38. Lee B, Kim Y, Lee H, Yi J, Micropor. Mesopor. Mater., 50, 77 (2001)