화학공학소재연구정보센터
Macromolecules, Vol.43, No.20, 8664-8669, 2010
Enhanced Mechanical Relaxation below the Glass Transition Temperature in Partially Supramolecular Networks
Cross-linked polymers in which part of the covalent cross-links have been replaced by reversible cross-links have potential application in coatings with improved stress relaxation. Here We present a detailed study of materials based on copolymers of epsilon-caprolactone and L-lactic acid, containing different ratios of covalent and ureidopyrimidinone(UPy) dimer cross-links. Their thermal and mechanical properties were tested by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and dielectric relaxation spectroscopy (DRS). By extrapolation of the alpha* relaxation process in DMA (arising from dynamics of the reversible UPy cross-links) to temperatures below the glass transition temperature (T-g), it was shown that the reversible cross-links contribute significantly to the relaxation of stress below T-g that was observed in creep measurements.