Mo Analysis of the Fluxional Behavior of M(Eta(3)-S(2)Cpme(3))(Co)(2)(PME(3))(2) (M=mo, W) Complexes

Galindo A; Mealli C

Inorganic Chemistry, Vol.35, No.8, 2406-2408, 1996

The fluxional behavior observed for the M(eta(3)-S-2-(CPMe(3))(CO)(2)(PMe(3))(2) (M = Mo, W) complexes is analyzed using a frontier orbital approach and extended Huckel calculations.

Keywords:CARBON-DISULFIDE;BONDING CAPABILITIES;MOLECULAR-STRUCTURES;TUNGSTEN COMPLEXES;MOLYBDENUM;LIGANDS;CRYSTAL;FRAGMENTS;TRIPHOS