Macromolecules, Vol.44, No.4, 976-980, 2011
Triptycene Polyimides: Soluble Polymers with High Thermal Stability and Low Refractive Indices
A series of soluble, thermally stable aromatic polyimides were synthesized using commercially available five- and six-membered ring anhydrides and 2,6-diaminotriptycene derivatives. All of these triptycene polyimides (TPls) were soluble in common organic solvents despite their completely aromatic structure due to the three-dimensional triptycene structure that prevents strong interchain interactions. Low solution viscosities (0.07-0.47 dL/g) and versatile solubilities allow for easy solution processing of these polymers. Nanoporosity in the solid state gives rise to high surface areas (up to 430 m(2)/g) and low refractive indices (1.19-1.79 at 633 nm), which suggest very low dielectric constants at optical frequencies. Polymer films were found to be amorphous. The decomposition temperature (T-d) for all of the polymers is above 500 degrees C, and no glass transition temperatures can be found below 450 degrees C by differential scanning calorimetry (DSC), indicating excellent prospects for high-temperature applications. This combination of properties makes these polymers candidates for spin-on dielectric materials.